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Do The following messages show that the pci_t32 will work fine ?
Warning (12188): OpenCore Plus Hardware Evaluation feature is turned on for the following cores
Warning (12190): ""PCI Compiler" (6AF7_0024)" will use the OpenCore Plus Hardware Evaluation feature
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No, that shows that Quartus doesn't recognise your license.
When you link to the license file in Quartus -> Help -> License Setup (I think I don't have Quartus here) if
it recognises and accepts the file it should list all the IP that's licensed in the window below.
Nial.