So this happened to me not to long ago as well. What happened is that when you switch the pin to a differential pin (probably by running the tcl script) it automatically created its differential counter part instead of using the already created pin. this means that memory_mem_ck created memory_mem_ck(n) as its differential pair instead of using the memory_ck_n pin. To solve this you can change the differential pair in the right column of the memory_mem_ck to the memeory_mem_ck_n. Do this for all your differential pins. the extra created pin should get removed automatically
For you oct_rzqin i am not familiar with that because i was using a ddr2 controller and there was not such pin.