You need to create an ALTPLL instance that will create a PLL in your design. The PLL will accept your 100MHz clock as input and produce a 25MHz clock as output.
From Quartus II:
1 - Tools->MegaWizard Plug-In Manager.
2 -Create a new custom megafunction variation.
3 - Select the I/O category on the left.
4 - Then select the ALTPLL megafunction.
5 - Give your file a name and click next. The megawizard will launch. Read the documentation if you need to. At the end of the day you'll have a verilog or vhdl module that you can instantiate in your design.
Jake