Draw two waveforms one on top of the other, where the top one is the launch clock and the bottom one is the latch clock. Shift the bottom one to the right 90 degrees and you have a same-edge transfer, e.g. when a rising edge launches data, a rising edge latches it, and when a falling edge launches data, a falling edge latches it.
Now do the same thing but shift the latch clock 90 degrees to the left(or the launch clock 90 degrees to the right, same thing). When a rising edge launches data, a falling edge latches it, and vice versa. This is opposite edge.
That being said, I strongly recommend against adding the false paths. They don't help in any way and can only hurt. Let's go back to the same edge transfer example. When data is launched from the rising edge at time 0 degrees, it will be latched 90 degrees later by the rising edge capture flip-flop. But it will also be captured 270 degrees later by the falling edge flip-flop(these are two distinct paths and TQ will analyze both). The only thing the false-path does is cut that 270 degree setup transfer. But if you meet the more-restrictive and correct 90 degree transfer, then you've automatically met that much less restrictive rise->fall 270 degree transfer. So it doesn't help meet timing. But let's say you put the same edge transfer false paths in, but made a mistake as your setup is really opposite edge. In that case you're cutting the correct 90 degree transfer and leaving the incorrect 270 degree transrer. Your design will easily meet timing because you cut the correct, restrictive one.
So there's pretty much nothing to gain and a lot to loose, so just leave them out.
If you want to spend some time reading about it, I put together the following:
http://www.alterawiki.com/uploads/e/ea/source_synchronous_timing.pdf#page=44