QSF and PIN file dont match

hello all, i'm very new to the area ,and dealing with few issues.

i'm using the quartos II 8.2 version , i added few pins to a working design , both to the design and to the QSF file ,

after the run of the proccess i checked the .PIN output file , and none of the new added signal/pins were included (it said they are user preserved but didnt call them by my names.) ,

does anybody have a clue?

(i have been checking other and older posts but didnt find the answer)

Thanks.