--- Quote Start ---
Is the exposed pad of the Cyclone III connected to ground?
--- Quote End ---
I also thought about this point, it's explicitely shown in the schematic. I wonder, if the pin is also known to be soldered correctly?
--- Quote Start ---
at beginning system connects only 3.3V bus, when it is done CONF_DONE looks like in attachment, then 3.3V is off, and then all supplies are on togheter
--- Quote End ---
I'm not sure, what you are describing here. Is it about a irregular power-up sequence?
According to the hardware manual, schottky diode should be used as AS clamp diodes, I assume that the LED symbols have been used by mistake.